化工新型材料

化工新型材料 ›› 2020, Vol. 48 ›› Issue (11) : 171-174. DOI: 10.19817/j.cnki.issn 1006-3536.2020.11.038

科学研究

微波改性柠檬渣吸附Cu²⁺的研究与回归分析

沈王庆, 王海燕

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Regression analysis and study on the adsorption of Cu²⁺ by microwave modifed lemon residue

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摘要

为了研究柠檬渣微波改性后对Cu²⁺的吸附性能。利用紫外光谱(UV)、红外光谱(FT-IR)、差热分析(TG-DTA)和能谱(EDS)对柠檬渣进行表征,并进行回归分析。结果表明:用微波改性后的柠檬渣对Cu²⁺的吸附率是预处理后柠檬渣的14.5倍左右,是化学改性后柠檬渣的1.23倍左右;微波产生的内酯基和酸性基团羧基,对Cu²⁺的吸附更有利;吸附Cu²⁺的柠檬渣较微波后的柠檬渣的最大吸收UV波长发生了蓝移,且振动范围变宽了;吸附Cu²⁺后的柠檬渣的TG线有3个失重过程;Cu²⁺能被改性柠檬渣有效吸附。相同拟合条件下,柠檬渣吸附Cu²⁺后的UV、FT-IR和DTA的出峰位置与峰强的拟合程度变差。

Abstract

In order to study the adsorption properties of Cu²⁺ by microwave modified lemon residues,the samples were characterized by UV,FT-IR,TG-DTA,EDS,and regression analysis was used too.The result shown that the adsorption rate of Cu²⁺ by the lemon residues was 14.5 times than by the pretreatment,and 1.23 times by chemical modified lemon residues.The lactone groups and the carboxyl groups of the acidic groups produced by the microwave were more favorable for the adsorption of Cu²⁺.The maximum absorption UV wavelength of the lemon residues after Cu²⁺ adsorption was increased than the microwave modified lemon residues,and the vibration range became wider.There were three weight loss processes to the TG line of the lemon residue after Cu²⁺ adsorption.Cu²⁺ could be effectively adsorbed by the modified lemon residue.The degree of fitting of the peak position and the peak intensity that the UV,FT-IR and DTA of lemon residues after Cu²⁺ adsorption was worse.

关键词

柠檬渣 / 微波 / 吸附 / 回归

Key words

lemon residue / microwave / adsorption / regression

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微波改性柠檬渣吸附Cu²⁺的研究与回归分析[J]. 化工新型材料, 2020, 48(11): 171-174 DOI:10.19817/j.cnki.issn 1006-3536.2020.11.038

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